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"http://vocab.nerc.ac.uk/collection/R03/current/BETA_BACKSCATTERING532/", "sensor": "BACKSCATTERINGMETER_BBP532", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "BETA_BACKSCATTERING700", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BETA_BACKSCATTERING700/", "sensor": "BACKSCATTERINGMETER_BBP700", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "CHLA", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/CHLA/", "sensor": "FLUOROMETER_CHLA", "units": "mg/m3", "accuracy": "0.08", "resolution": "0.025", "predeployment_calib_equation": "CHLA=(FLUORESCENCE_CHLA-DARK_CHLA)*SCALE_CHLA;", "predeployment_calib_coefficient": "SCALE_CHLA=1.661E-03;DARK_CHLA=49;", "predeployment_calib_comment": "" }, { "name": "BBP532", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BBP532/", "sensor": "BACKSCATTERINGMETER_BBP532", "units": "m-1", "accuracy": "", "resolution": "", "predeployment_calib_equation": "BBP532=2*pi*khi *((BETA_BACKSCATTERING532-DARK_BACKSCATTERING532)*SCALE_BACKSCATTERING532-BETASW532);", "predeployment_calib_coefficient": "DARK_BACKSCATTERING532=50;SCALE_BACKSCATTERING532=1.263E-06;khi=1.076;BETASW532 (contribution of pure sea water) is calculated at 124 deg;", "predeployment_calib_comment": "" }, { "name": "BBP700", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BBP700/", "sensor": "BACKSCATTERINGMETER_BBP700", "units": "m-1", "accuracy": "", "resolution": "", "predeployment_calib_equation": "BBP700=2*pi*khi *((BETA_BACKSCATTERING700-DARK_BACKSCATTERING700)*SCALE_BACKSCATTERING700-BETASW700);", "predeployment_calib_coefficient": "DARK_BACKSCATTERING700=48;SCALE_BACKSCATTERING700=3.581E-07;khi=1.076;BETASW700 (contribution of pure sea water) is calculated at 150 deg;", "predeployment_calib_comment": "" }, { "name": "TEMP_NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/TEMP_NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "degree_Celsius", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "TEMP_SPECTROPHOTOMETER_NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/TEMP_SPECTROPHOTOMETER_NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "degree_Celsius", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "HUMIDITY_NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/HUMIDITY_NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "percent", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "UV_INTENSITY_DARK_NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/UV_INTENSITY_DARK_NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "FIT_ERROR_NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/FIT_ERROR_NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "dimensionless", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "UV_INTENSITY_NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/UV_INTENSITY_NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "NITRATE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/NITRATE/", "sensor": "SPECTROPHOTOMETER_NITRATE", "units": "umol/kg", "accuracy": "2", "resolution": "0.01", "predeployment_calib_equation": "The sensor returns UV_INTENSITY_DARK_NITRATE and UV_INTENSITY_NITRATE(Ntrans), a subset of continuous pixels of UV_INTENSITY_NITRATE(N), N = 1 to 256. The Ntrans indices span the interval [PIXEL_START, PIXEL_END] subset of the original array (1 to 256). Thus Ntrans(i) refers to pixel N = (PIXEL_START+i-1). PIXEL_START and PIXEL_END are defined from calibration data so that the [PIXEL_START, PIXEL_END] interval is the smallest interval of pixels that correspond to the [217 nm, 250 nm] interval of wavelengths. Only a subset of the [PIXEL_START, PIXEL_END] interval is processed to compute nitrate concentration. This subset is defined as the [PIXEL_FIT_START, PIXEL_FIT_END] interval which is the smallest interval of pixels that correspond to the [217 nm, 240 nm] interval of wavelengths (thus PIXEL_FIT_START = PIXEL_START). In the following equations the data are computed for each pixel R = PIXEL_FIT_START to PIXEL_FIT_END; ABSORBANCE_SW(R)=-log10[(UV_INTENSITY_NITRATE(R)-UV_INTENSITY_DARK_NITRATE)/UV_INTENSITY_REF_NITRATE(R)]; F(R,T)=(A+B*T)*exp[(C+D*T)*(OPTICAL_WAVELENGTH_UV(R)-OPTICAL_WAVELENGTH_OFFSET)]; E_SWA_INSITU(R)=E_SWA_NITRATE(R)*F(R,TEMP)/F(R,TEMP_CAL_NITRATE); ABSORBANCE_COR_NITRATE(R)=ABSORBANCE_SW(R)-(E_SWA_INSITU(R)*PSAL)*[1-(0.026*PRES/1000)]; Perform a multilinear regression to get MOLAR_NITRATE with estimated ABSORBANCE_COR_NITRATE(R) with ABSORBANCE_COR_NITRATE(R)=BASELINE_INTERCEPT+BASELINE_SLOPE*OPTICAL_WAVELENGTH_UV(R)+MOLAR_NITRATE*E_NITRATE(R); NITRATE=MOLAR_NITRATE/rho, where rho is the potential density [kg/L] calculated from CTD data.", "predeployment_calib_coefficient": "n/a", "predeployment_calib_comment": "" }, { "name": "VRS_PH", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/VRS_PH/", "sensor": "TRANSISTOR_PH", "units": "volt", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "PH_IN_SITU_FREE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PH_IN_SITU_FREE/", "sensor": "TRANSISTOR_PH", "units": "dimensionless", "accuracy": "0.005", "resolution": "0.0004", "predeployment_calib_equation": "k0T=k0+k2*TEMP; pcorr=f1*PRES+f2*PRES^2+f3*PRES^3+f4*PRES^4+f5*PRES^5+f6*PRES^6; k0TP=k0T+pcorr; Tk=273.15+TEMP; Cltotal=(0.99889/35.453*PSAL/1.80655)/(1-0.001005*PSAL); ADH=3.4286e-6*TEMP^2+6.7524e-4*TEMP+0.49172143; IonS=19.924*PSAL/(1000-1.005*PSAL); log10gammaHCl=[-ADH*sqrt(IonS)/(1+1.394*sqrt(IonS))]+[(0.08885-0.000111*TEMP)*IonS]; deltaVHCl=17.85+0.1044*TEMP-0.001316*TEMP^2; log10gammaHCLtP=log10gammaHCl+[deltaVHCl*(PRES/10)/(R*Tk*ln(10))/2/10]; PH_IN_SITU_FREE=[(VRS_PH-k0TP)/(R*Tk/F*ln(10))]+[ln(Cltotal)/ln(10)]+2*log10gammaHCLtP-log10(1-0.001005*PSAL); Stotal=(0.14/96.062)*(PSAL/1.80655); Khso4=exp{[-4276.1/Tk+141.328-23.093*ln(Tk)]+[(-13856/Tk+324.57-47.986*ln(Tk))*IonS^0.5]+[(35474/Tk-771.54+114.723*ln(Tk))*IonS]-[2698/Tk*IonS^1.5]+[1776/Tk*IonS^2]+ln(1-0.001005*PSAL)}; deltaVHSO4=-18.03+0.0466*TEMP+0.000316*TEMP^2; KappaHSO4=(-4.53+0.09*TEMP)/1000; lnKhso4fac=(-deltaVHSO4+0.5*KappaHSO4*(PRES/10))*(PRES/10)/(R*10*Tk); Khso4TPS=Khso4*exp(lnKhso4fac); PH_IN_SITU_TOTAL=PH_IN_SITU_FREE-log10(1+Stotal/Khso4TPS)", "predeployment_calib_coefficient": "R=8.31446;F=96485;k0=-1.2902;k2=-0.00084218;f0=-0.00092842;f1=3.6221e-06;f2=-2.4072e-09;f3=-7.9741e-13;f4=2.3507e-15;f5=-1.2389e-18;f6=2.1171e-22;", "predeployment_calib_comment": "" }, { "name": "PH_IN_SITU_TOTAL", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PH_IN_SITU_TOTAL/", "sensor": "TRANSISTOR_PH", "units": "dimensionless", "accuracy": "0.005", "resolution": "0.0004", "predeployment_calib_equation": "k0T=k0+k2*TEMP; pcorr=f1*PRES+f2*PRES^2+f3*PRES^3+f4*PRES^4+f5*PRES^5+f6*PRES^6; k0TP=k0T+pcorr; Tk=273.15+TEMP; Cltotal=(0.99889/35.453*PSAL/1.80655)/(1-0.001005*PSAL); ADH=3.4286e-6*TEMP^2+6.7524e-4*TEMP+0.49172143; IonS=19.924*PSAL/(1000-1.005*PSAL); log10gammaHCl=[-ADH*sqrt(IonS)/(1+1.394*sqrt(IonS))]+[(0.08885-0.000111*TEMP)*IonS]; deltaVHCl=17.85+0.1044*TEMP-0.001316*TEMP^2; log10gammaHCLtP=log10gammaHCl+[deltaVHCl*(PRES/10)/(R*Tk*ln(10))/2/10]; PH_IN_SITU_FREE=[(VRS_PH-k0TP)/(R*Tk/F*ln(10))]+[ln(Cltotal)/ln(10)]+2*log10gammaHCLtP-log10(1-0.001005*PSAL); Stotal=(0.14/96.062)*(PSAL/1.80655); Khso4=exp{[-4276.1/Tk+141.328-23.093*ln(Tk)]+[(-13856/Tk+324.57-47.986*ln(Tk))*IonS^0.5]+[(35474/Tk-771.54+114.723*ln(Tk))*IonS]-[2698/Tk*IonS^1.5]+[1776/Tk*IonS^2]+ln(1-0.001005*PSAL)}; deltaVHSO4=-18.03+0.0466*TEMP+0.000316*TEMP^2; KappaHSO4=(-4.53+0.09*TEMP)/1000; lnKhso4fac=(-deltaVHSO4+0.5*KappaHSO4*(PRES/10))*(PRES/10)/(R*10*Tk); Khso4TPS=Khso4*exp(lnKhso4fac); PH_IN_SITU_TOTAL=PH_IN_SITU_FREE-log10(1+Stotal/Khso4TPS)", "predeployment_calib_coefficient": "R=8.31446;F=96485;k0=-1.2902;k2=-0.00084218;f0=-0.00092842;f1=3.6221e-06;f2=-2.4072e-09;f3=-7.9741e-13;f4=2.3507e-15;f5=-1.2389e-18;f6=2.1171e-22;", "predeployment_calib_comment": "" } ], "sci:doi": "10.17882/42182", "sci:citation": "Argo (2024). 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