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"PRES", "PHASE_DELAY_DOXY", "TEMP_VOLTAGE_DOXY", "TEMP_DOXY", "DOXY", "PPOX_DOXY", "FLUORESCENCE_CHLA", "BETA_BACKSCATTERING532", "BETA_BACKSCATTERING700", "CHLA", "BBP532", "BBP700", "VRS_PH", "PH_IN_SITU_FREE", "PH_IN_SITU_TOTAL" ], "instruments": [ "CTD_CNDC", "CTD_TEMP", "CTD_PRES", "OPTODE_DOXY", "FLUOROMETER_CHLA", "BACKSCATTERINGMETER_BBP532", "BACKSCATTERINGMETER_BBP700", "TRANSISTOR_PH" ], "mission": "CHINA ARGO", "sensors": [ { "name": "CTD_CNDC", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/CTD_CNDC/", "maker": "SBE", "model": "SBE41N_V5.3.5", "serial_no": "17702" }, { "name": "CTD_TEMP", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/CTD_TEMP/", "maker": "SBE", "model": "SBE41N_V5.3.5", "serial_no": "17702" }, { "name": "CTD_PRES", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/CTD_PRES/", "maker": "DRUCK", "model": "DRUCK_2900PSIA", "serial_no": "12133212" }, { "name": "OPTODE_DOXY", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/OPTODE_DOXY/", "maker": "SBE", "model": "SBE63_OPTODE", "serial_no": "3150" }, { "name": "FLUOROMETER_CHLA", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/FLUOROMETER_CHLA/", "maker": "WETLABS", "model": "MCOMS_FLBB2", "serial_no": "MCOMSB-0356" }, { "name": "BACKSCATTERINGMETER_BBP532", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/BACKSCATTERINGMETER_BBP532/", "maker": "WETLABS", "model": "MCOMS_FLBB2", "serial_no": "MCOMSB-0356" }, { "name": "BACKSCATTERINGMETER_BBP700", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/BACKSCATTERINGMETER_BBP700/", "maker": "WETLABS", "model": "MCOMS_FLBB2", "serial_no": "MCOMSB-0356" }, { "name": "TRANSISTOR_PH", "URI_sensor": "http://vocab.nerc.ac.uk/collection/R25/current/TRANSISTOR_PH/", "maker": "SBE", "model": "SEAFET", "serial_no": "11297" } ], "detailed_parameters": [ { "name": "PSAL", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PSAL/", "sensor": "CTD_CNDC", "units": "psu", "accuracy": "0.005", "resolution": "0.001", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "TEMP", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/TEMP/", "sensor": "CTD_TEMP", "units": "degree_Celsius", "accuracy": "0.002", "resolution": "0.001", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "PRES", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PRES/", "sensor": "CTD_PRES", "units": "decibar", "accuracy": "2.4", "resolution": "0.1", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "PHASE_DELAY_DOXY", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PHASE_DELAY_DOXY/", "sensor": "OPTODE_DOXY", "units": "microsecond", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "TEMP_VOLTAGE_DOXY", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/TEMP_VOLTAGE_DOXY/", "sensor": "OPTODE_DOXY", "units": "volts", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "TEMP_DOXY", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/TEMP_DOXY/", "sensor": "OPTODE_DOXY", "units": "degree_Celsius", "accuracy": "", "resolution": "", "predeployment_calib_equation": "temp_doxy=1/(ta0+(ta1*L)+(ta2*L^2)+(ta3*L^3))-273.15;", "predeployment_calib_coefficient": "ta0=7.181463e-004;ta1=2.470098e-004;ta2=1.082408e-006;ta3=8.583946e-008;", "predeployment_calib_comment": "" }, { "name": "DOXY", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/DOXY/", "sensor": "OPTODE_DOXY", "units": "micromole/kg", "accuracy": "5", "resolution": "0.4", "predeployment_calib_equation": "V=(PHASE_DELAY_DOXY+Pcoef1*PRES/1000)/39.457071; Ksv=C0+C1*TEMP_DOXY+C2*TEMP_DOXY^2; MLPL_DOXY=[(A0+A1*TEMP_DOXY+A2*V^2)/(B0+B1*V)-1]/Ksv; O2=MLPL_DOXY*Scorr*Pcorr; Scorr=A*exp[PSAL*(SolB0+SolB1*TS+SolB2*TS^2+SolB3*TS^3)+SolC0*PSAL^2]; A=[(1013.25-pH2O(TEMP,Spreset))/(1013.25-pH2O(TEMP,PSAL))]; pH2O(TEMP,S)=1013.25*exp[D0+D1*(100/(TEMP+273.15))+D2*ln((TEMP+273.15) /100)+D3*S]; Pcorr=1+((Pcoef2*TEMP+Pcoef3)*PRES)/1000; TS=ln[(298.15-TEMP)/(273.15+TEMP)]; DOXY[umol/kg]=44.6596*O2/rho, where rho is the potential density [kg/L] calculated from CTD data", "predeployment_calib_coefficient": "Pcoef1=0.115, Pcoef2=0.00022, Pcoef3=0.0419; A0=1.0513, A1=-1.5e-03, A2=3.765042e-01; B0=-2.478127e-001, B1=1.607957e+000; C0=1.096101e-001, C1=4.673368e-003, C2=6.56963e-005;E=1.1e-02;Spreset=0; D0=24.4543, D1=-67.4509, D2=-4.8489, D3=-5.44e-4; SolB0=-6.24523e-3, SolB1=-7.37614e-3, SolB2=-1.03410e-3, SolB3=-8.17083e-3; SolC0=-4.88682e-7;", "predeployment_calib_comment": "" }, { "name": "PPOX_DOXY", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PPOX_DOXY/", "sensor": "OPTODE_DOXY", "units": "mbar", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "FLUORESCENCE_CHLA", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/FLUORESCENCE_CHLA/", "sensor": "FLUOROMETER_CHLA", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "BETA_BACKSCATTERING532", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BETA_BACKSCATTERING532/", "sensor": "BACKSCATTERINGMETER_BBP532", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "BETA_BACKSCATTERING700", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BETA_BACKSCATTERING700/", "sensor": "BACKSCATTERINGMETER_BBP700", "units": "count", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "CHLA", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/CHLA/", "sensor": "FLUOROMETER_CHLA", "units": "mg/m3", "accuracy": "0.08", "resolution": "0.025", "predeployment_calib_equation": "CHLA=(FLUORESCENCE_CHLA-DARK_CHLA)*SCALE_CHLA;", "predeployment_calib_coefficient": "SCALE_CHLA=2.030E-03;DARK_CHLA=49;", "predeployment_calib_comment": "" }, { "name": "BBP532", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BBP532/", "sensor": "BACKSCATTERINGMETER_BBP532", "units": "m-1", "accuracy": "", "resolution": "", "predeployment_calib_equation": "BBP532=2*pi*khi *((BETA_BACKSCATTERING532-DARK_BACKSCATTERING532)*SCALE_BACKSCATTERING532-BETASW532);", "predeployment_calib_coefficient": "DARK_BACKSCATTERING532=50;SCALE_BACKSCATTERING532=1.397E-06;khi=1.076;BETASW532 (contribution of pure sea water) is calculated at 124 deg;", "predeployment_calib_comment": "" }, { "name": "BBP700", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/BBP700/", "sensor": "BACKSCATTERINGMETER_BBP700", "units": "m-1", "accuracy": "", "resolution": "", "predeployment_calib_equation": "BBP700=2*pi*khi *((BETA_BACKSCATTERING700-DARK_BACKSCATTERING700)*SCALE_BACKSCATTERING700-BETASW700);", "predeployment_calib_coefficient": "DARK_BACKSCATTERING700=48;SCALE_BACKSCATTERING700=3.485E-07;khi=1.076;BETASW700 (contribution of pure sea water) is calculated at 150 deg;", "predeployment_calib_comment": "" }, { "name": "VRS_PH", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/VRS_PH/", "sensor": "TRANSISTOR_PH", "units": "volt", "accuracy": "", "resolution": "", "predeployment_calib_equation": "none", "predeployment_calib_coefficient": "none", "predeployment_calib_comment": "" }, { "name": "PH_IN_SITU_FREE", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PH_IN_SITU_FREE/", "sensor": "TRANSISTOR_PH", "units": "dimensionless", "accuracy": "0.005", "resolution": "0.0004", "predeployment_calib_equation": "k0T=k0+k2*TEMP; pcorr=f1*PRES+f2*PRES^2+f3*PRES^3+f4*PRES^4+f5*PRES^5+f6*PRES^6; k0TP=k0T+pcorr; Tk=273.15+TEMP; Cltotal=(0.99889/35.453*PSAL/1.80655)/(1-0.001005*PSAL); ADH=3.4286e-6*TEMP^2+6.7524e-4*TEMP+0.49172143; IonS=19.924*PSAL/(1000-1.005*PSAL); log10gammaHCl=[-ADH*sqrt(IonS)/(1+1.394*sqrt(IonS))]+[(0.08885-0.000111*TEMP)*IonS]; deltaVHCl=17.85+0.1044*TEMP-0.001316*TEMP^2; log10gammaHCLtP=log10gammaHCl+[deltaVHCl*(PRES/10)/(R*Tk*ln(10))/2/10]; PH_IN_SITU_FREE=[(VRS_PH-k0TP)/(R*Tk/F*ln(10))]+[ln(Cltotal)/ln(10)]+2*log10gammaHCLtP-log10(1-0.001005*PSAL); Stotal=(0.14/96.062)*(PSAL/1.80655); Khso4=exp{[-4276.1/Tk+141.328-23.093*ln(Tk)]+[(-13856/Tk+324.57-47.986*ln(Tk))*IonS^0.5]+[(35474/Tk-771.54+114.723*ln(Tk))*IonS]-[2698/Tk*IonS^1.5]+[1776/Tk*IonS^2]+ln(1-0.001005*PSAL)}; deltaVHSO4=-18.03+0.0466*TEMP+0.000316*TEMP^2; KappaHSO4=(-4.53+0.09*TEMP)/1000; lnKhso4fac=(-deltaVHSO4+0.5*KappaHSO4*(PRES/10))*(PRES/10)/(R*10*Tk); Khso4TPS=Khso4*exp(lnKhso4fac); PH_IN_SITU_TOTAL=PH_IN_SITU_FREE-log10(1+Stotal/Khso4TPS)", "predeployment_calib_coefficient": "R=8.31446;F=96485;k0=-1.3397;k2=-0.0010173;f0=-0.0014466;f1=8.3489e-06;f2=-1.4192e-08;f3=1.4375e-11;f4=-8.2512e-15;f5=2.5384e-18;f6=-3.2428e-22;", "predeployment_calib_comment": "" }, { "name": "PH_IN_SITU_TOTAL", "URI_parameter": "http://vocab.nerc.ac.uk/collection/R03/current/PH_IN_SITU_TOTAL/", "sensor": "TRANSISTOR_PH", "units": "dimensionless", "accuracy": "0.005", "resolution": "0.0004", "predeployment_calib_equation": "k0T=k0+k2*TEMP; pcorr=f1*PRES+f2*PRES^2+f3*PRES^3+f4*PRES^4+f5*PRES^5+f6*PRES^6; k0TP=k0T+pcorr; Tk=273.15+TEMP; Cltotal=(0.99889/35.453*PSAL/1.80655)/(1-0.001005*PSAL); ADH=3.4286e-6*TEMP^2+6.7524e-4*TEMP+0.49172143; IonS=19.924*PSAL/(1000-1.005*PSAL); log10gammaHCl=[-ADH*sqrt(IonS)/(1+1.394*sqrt(IonS))]+[(0.08885-0.000111*TEMP)*IonS]; deltaVHCl=17.85+0.1044*TEMP-0.001316*TEMP^2; log10gammaHCLtP=log10gammaHCl+[deltaVHCl*(PRES/10)/(R*Tk*ln(10))/2/10]; PH_IN_SITU_FREE=[(VRS_PH-k0TP)/(R*Tk/F*ln(10))]+[ln(Cltotal)/ln(10)]+2*log10gammaHCLtP-log10(1-0.001005*PSAL); Stotal=(0.14/96.062)*(PSAL/1.80655); Khso4=exp{[-4276.1/Tk+141.328-23.093*ln(Tk)]+[(-13856/Tk+324.57-47.986*ln(Tk))*IonS^0.5]+[(35474/Tk-771.54+114.723*ln(Tk))*IonS]-[2698/Tk*IonS^1.5]+[1776/Tk*IonS^2]+ln(1-0.001005*PSAL)}; deltaVHSO4=-18.03+0.0466*TEMP+0.000316*TEMP^2; KappaHSO4=(-4.53+0.09*TEMP)/1000; lnKhso4fac=(-deltaVHSO4+0.5*KappaHSO4*(PRES/10))*(PRES/10)/(R*10*Tk); Khso4TPS=Khso4*exp(lnKhso4fac); PH_IN_SITU_TOTAL=PH_IN_SITU_FREE-log10(1+Stotal/Khso4TPS)", "predeployment_calib_coefficient": "R=8.31446;F=96485;k0=-1.3397;k2=-0.0010173;f0=-0.0014466;f1=8.3489e-06;f2=-1.4192e-08;f3=1.4375e-11;f4=-8.2512e-15;f5=2.5384e-18;f6=-3.2428e-22;", "predeployment_calib_comment": "" } ], "sci:doi": "10.17882/42182", "sci:citation": "Argo (2024). 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